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4, 4′-Methylene bis (2-chloraniline) and/or salts, in powder form 101-14-4 0,01 24. Methylisocyanate 624-83-9 0,15 25. Oxygen 7782-44-7 200 2 000 26. 2,4 -Toluene diisocyanate 584-84-9 10 100 2,6 -Toluene diisocyanate 91-08-7 27. Carbonyl dichloride (phosgene) 75-44-5 0,3 0,75 28. Arsine (arsenic trihydride) 7784-42-1 0,2 1 29. Phosphine (phosphorus trihydride) 7803-51-2 0,2 1 30. Sulphur dichloride 10545-99-0 1 31. Sulphur trioxide 7446-11-9 15 75 32. Polychlorodibenzofurans and polychlorodibenzodioxins (including TCDD), calculated in TCDD equivalent (see note 20) — 0,001 33. The following CARCINOGENS or the mixtures containing the following carcinogens at concentrations above 5 % by weight: 4-Aminobiphenyl and/or its salts, Benzotrichloride, Benzidine and/or salts, Bis (chloromethyl) ether, Chloromethyl methyl ether, 1,2-Dibromoethane, Diethyl sulphate, Dimethyl sulphate, Dimethylcarbamoyl chloride, 1,2-Dibromo-3-chloropropane, 1,2-Dimethylhydrazine, Dimethylnitrosamine, Hexamethylphosphoric triamide, Hydrazine, 2- Naphthylamine and/or salts, 4-Nitrodiphenyl, and 1,3 Propanesultone — 0,5 2 34. Petroleum products and alternative fuels (a) gasolines and naphthas, (b) kerosenes (including jet fuels), (c) gas oils (including diesel fuels, home heating oils and gas oil blending streams) (d) heavy fuel oils (e) alternative fuels serving the same purposes and with similar properties as regards flammability and environmental hazards as the products referred to in points (a) to (d) — 2 500 25 000 35. Anhydrous Ammonia 7664-41-7 50 200 36. Boron trifluoride 7637-07-2 5 20 37. Hydrogen sulphide 7783-06-4 5 20 38. Piperidine 110-89-4 50 200 39. Bis(2-dimethylaminoethyl) (methyl)amin 3030-47-5 50 200 40. 3-(2-Ethylhexyloxy)propylamin 5397-31-9 50 200 41. Mixtures of sodium hypochlorite classified as Aquatic Acute Category 1 [H400] containing less than 5 % active chlorine and not classified under any of the other hazard categories in Part 1 of Annex I

5. In the case of dangerous substances which are not covered by Regulation (EC) No 1272/2008, including waste, but which nevertheless are present, or are likely to be present, in an establishment and which possess or are likely to possess, under the conditions found at the establishment, equivalent properties in terms of major-accident potential, these shall be provisionally assigned to the most analogous category or named dangerous substance falling within the scope of this Directive.

6. In the case of dangerous substances with properties giving rise to more than one classification, for the purposes of this Directive the lowest qualifying quantities shall apply. However, for the application of the rule in Note 4, the lowest qualifying quantity for each group of categories in Notes 4(a), 4(b) and 4(c) corresponding to the classification concerned shall be used.

DANGEROUS SUBSTANCES Dangerous substances covered by the hazard categories listed in Column 1 of Part 1 of this Annex are subject to the qualifying quantities set out in Columns 2 and 3 of Part 1. Where a dangerous substance is covered by Part 1 of this Annex and is also listed in Part 2, the qualifying quantities set out in Columns 2 and 3 of Part 2 apply. PART 1 Categories of dangerous substances This Part covers all dangerous substances falling under the hazard categories listed in Column 1:

Column 1 Column 2 Column 3 Hazard categories in accordance with Regulation (EC) No 1272/2008 Qualifying quantity (tonnes) of dangerous substances as referred to in Article 3(10) for the application of Lower-tier requirements Upper-tier requirements Section ‘H’ – HEALTH HAZARDS H1 ACUTE TOXIC Category 1, all exposure routes 5 20 H2 ACUTE TOXIC — Category 2, all exposure routes — Category 3, inhalation exposure route (see note 7) 50 200 H3 STOT SPECIFIC TARGET ORGAN TOXICITY – SINGLE EXPOSURE STOT SE Category 1 50 200 Section ‘P’ – PHYSICAL HAZARDS P1a EXPLOSIVES (see note 8) — Unstable explosives or — Explosives, Division 1.1, 1.2, 1.3, 1.5 or 1.6, or — Substances or mixtures having explosive properties according to method A.14 of Regulation (EC) No 440/2008 (see note 9) and do not belong to the hazard classes Organic peroxides or Self-reactive substances and mixtures 10 50 P1b EXPLOSIVES (see note 8) Explosives, Division 1.4 (see note 10) 50 200 P2 FLAMMABLE GASES Flammable gases, Category 1 or 2 10 50 P3a FLAMMABLE AEROSOLS (see note 11.1) ‘Flammable’ aerosols Category 1 or 2, containing flammable gases Category 1 or 2 or flammable liquids Category 1 150 (net) 500 (net) P3b FLAMMABLE AEROSOLS (see note 11.1) ‘Flammable’ aerosols Category 1 or 2, not containing flammable gases Category 1 or 2 nor flammable liquids category 1 (see note 11.2) 5 000 (net) 50 000 (net) P4 OXIDISING GASES Oxidising gases, Category 1 50 200 P5a FLAMMABLE LIQUIDS — Flammable liquids, Category 1, or — Flammable liquids Category 2 or 3 maintained at a temperature above their boiling point, or — Other liquids with a flash point ≤ 60 °C, maintained at a temperature above their boiling point (see note 12) 10 50 P5b FLAMMABLE LIQUIDS — Flammable liquids Category 2 or 3 where particular processing conditions, such as high pressure or high temperature, may create major-accident hazards, or — Other liquids with a flash point ≤ 60 °C where particular processing conditions, such as high pressure or high temperature, may create major-accident hazards (see note 12) 50 200 P5c FLAMMABLE LIQUIDS Flammable liquids, Categories 2 or 3 not covered by P5a and P5b 5 000 50 000 P6a SELF-REACTIVE SUBSTANCES AND MIXTURES and ORGANIC PEROXIDES Self-reactive substances and mixtures, Type A or B or organic peroxides, Type A or B 10 50 P6b SELF-REACTIVE SUBSTANCES AND MIXTURES and ORGANIC PEROXIDES Self-reactive substances and mixtures, Type C, D, E or F or organic peroxides, Type C, D, E, or F 50 200 P7 PYROPHORIC LIQUIDS AND SOLIDS Pyrophoric liquids, Category 1 Pyrophoric solids, Category 1 50 200 P8 OXIDISING LIQUIDS AND SOLIDS Oxidising Liquids, Category 1, 2 or 3, or Oxidising Solids, Category 1, 2 or 3 50 200 Section ‘E’ – ENVIRONMENTAL HAZARDS E1 Hazardous to the Aquatic Environment in Category Acute 1 or Chronic 1 100 200 E2 Hazardous to the Aquatic Environment in Category Chronic 2 200 500 Section ‘O’ – OTHER HAZARDS O1 Substances or mixtures with hazard statement EUH014 100 500 O2 Substances and mixtures which in contact with water emit flammable gases, Category 1 100 500 O3 Substances or mixtures with hazard statement EUH029 50 200

Column 1 CAS number Column 2 Column 3 Qualifying quantity (tonnes) for the application of Dangerous substances Lower-tier requirements Upper-tier requirements 1. Ammonium nitrate (see note 13) — 5 000 10 000 2. Ammonium nitrate (see note 14) — 1 250 5 000 3. Ammonium nitrate (see note 15) — 350 2 500 4. Ammonium nitrate (see note 16) — 10 50 5. Potassium nitrate (see note 17) — 5 000 10 000 6. Potassium nitrate (see note 18) — 1 250 5 000 7. Arsenic pentoxide, arsenic (V) acid and/or salts 1303-28-2 1 2 8. Arsenic trioxide, arsenious (III) acid and/or salts 1327-53-3 0,1 9. Bromine 7726-95-6 20 100 10. Chlorine 7782-50-5 10 25 11. Nickel compounds in inhalable powder form: nickel monoxide, nickel dioxide, nickel sulphide, trinickel disulphide, dinickel trioxide — 1 12. Ethyleneimine 151-56-4 10 20 13. Fluorine 7782-41-4 10 20 14. Formaldehyde (concentration ≥ 90 %) 50-00-0 5 50 15. Hydrogen 1333-74-0 5 50 16. Hydrogen chloride (liquefied gas) 7647-01-0 25 250 17. Lead alkyls — 5 50 18. Liquefied flammable gases, Category 1 or 2 (including LPG) and natural gas (see note 19) — 50 200 19. Acetylene 74-86-2 5 50 20. Ethylene oxide 75-21-8 5 50 21. Propylene oxide 75-56-9 5 50 22. Methanol 67-56-1 500 5 000 23

200 500 42. Propylamine (see note 21) 107-10-8 500 2 000 43. Tert-butyl acrylate (see note 21) 1663-39-4 200 500 44. 2-Methyl-3-butenenitrile (see note 21) 16529-56-9 500 2 000 45. Tetrahydro-3,5-dimethyl-1,3,5,-thiadiazine-2-thione (Dazomet) (see note 21) 533-74-4 100 200 46. Methyl acrylate (see note 21) 96-33-3 500 2 000 47. 3-Methylpyridine (see note 21) 108-99-6 500 2 000 48. 1-Bromo-3-chloropropane (see note 21) 109-70-6 500 2 000 NOTES TO ANNEX I 1. Substances and mixtures are classified in accordance with Regulation (EC) No 1272/2008.

2. Mixtures shall be treated in the same way as pure substances provided they remain within concentration limits set according to their properties under Regulation (EC) No 1272/2008, or its latest adaptation to technical progress, unless a percentage composition or other description is specifically given.

3. The qualifying quantities set out above relate to each establishment. The quantities to be considered for the application of the relevant Articles are the maximum quantities which are present or are likely to be present at any one time. Dangerous substances present at an establishment only in quantities equal to or less than 2 % of the relevant qualifying quantity shall be ignored for the purposes of calculating the total quantity present if their location within an establishment is such that it cannot act as an initiator of a major accident elsewhere at that establishment.

4. The following rules governing the addition of dangerous substances, or categories of dangerous substances, shall apply where appropriate: In the case of an establishment where no individual dangerous substance is present in a quantity above or equal to the relevant qualifying quantities, the following rule shall be applied to determine whether the establishment is covered by the relevant requirements of this Directive. This Directive shall apply to upper-tier establishments if the sum: q1/QU1 + q2/QU2 + q3/QU3 + q4/QU4 + q5/QU5 + … is greater than or equal to 1, where qx = the quantity of dangerous substance x (or category of dangerous substances) falling within Part 1 or Part 2 of this Annex, and QUX = the relevant qualifying quantity for dangerous substance or category x from Column 3 of Part 1 or from Column 3 of Part 2 of this Annex. This Directive shall apply to lower-tier establishments if the sum: q1/QL1 + q2/QL2 + q3/QL3 + q4/QL4 + q5/QL5 + … is greater than or equal to 1, where qx = the quantity of dangerous substance x (or category of dangerous substances) falling within Part 1 or Part 2 of this Annex, and QLX = the relevant qualifying quantity for dangerous substance or category x from Column 2 of Part 1 or from Column 2 of Part 2 of this Annex. This rule shall be used to assess the health hazards, physical hazards and environmental hazards. It must therefore be applied three times:

(a) for the addition of dangerous substances listed in Part 2 that fall within acute toxicity category 1, 2 or 3 (inhalation route) or STOT SE category 1, together with dangerous substances falling within section H, entries H1 to H3 of Part 1;

(b) for the addition of dangerous substances listed in Part 2 that are explosives, flammable gases, flammable aerosols, oxidising gases, flammable liquids, self-reactive substances and mixtures, organic peroxides, pyrophoric liquids and solids, oxidising liquids and solids, together with dangerous substances falling within section P, entries P1 to P8 of Part 1;

(c) for the addition of dangerous substances listed in Part 2 that fall within hazardous to the aquatic environment acute category 1, chronic category 1 or chronic category 2, together with dangerous substances falling within section E, entries E1 and E2 of Part 1. The relevant provisions of this Directive apply where any of the sums obtained by (a), (b) or (c) is greater than or equal to 1.

7. Dangerous substances that fall within Acute Toxic Category 3 via the oral route (H 301) shall fall under entry H2 ACUTE TOXIC in those cases where neither acute inhalation toxicity classification nor acute dermal toxicity classification can be derived, for example due to lack of conclusive inhalation and dermal toxicity data.

8. The hazard class Explosives includes explosive articles (see Section 2.1 of Annex I to Regulation (EC) No 1272/2008). If the quantity of the explosive substance or mixture contained in the article is known, that quantity shall be considered for the purposes of this Directive. If the quantity of the explosive substance or mixture contained in the article is not known, then, for the purposes of this Directive, the whole article shall be treated as explosive.

9. Testing for explosive properties of substances and mixtures is only necessary if the screening procedure according to Appendix 6, Part 3 of the UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria (UN Manual of Tests and Criteria) identifies the substance or mixture as potentially having explosive properties.

10. If Explosives of Division 1.4 are unpacked or repacked, they shall be assigned to the entry P1a, unless the hazard is shown to still correspond to Division 1.4, in accordance with Regulation (EC) No 1272/2008.

11.1. Flammable aerosols are classified in accordance with the Council Directive 75/324/EEC of 20 May 1975 on the approximation of the laws of the Member States relating to aerosol dispensers (Aerosol Dispensers Directive). ‘Extremely flammable’ and ‘Flammable’ aerosols of Directive 75/324/EEC correspond to Flammable Aerosols Category 1 or 2 respectively of Regulation (EC) No 1272/2008.

11.2. In order to use this entry, it must be documented that the aerosol dispenser does not contain Flammable Gas Category 1 or 2 nor Flammable Liquid Category 1.